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Chemcial Industry and Engineering 2005, Vol. 22 Issue (1) :4-7    DOI:
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Adsorption Kinetics of Surfactant at Air/Solution Interface
LIU Jun-ji, WANG Chuang-ye, XU Ling(School of Sciences,Tianjin University,Tianjin 300072,China)
(School of Sciences,Tianjin University,Tianjin 300072,China

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Abstract The diffusion equation was solved and the dynamic surface adsorption Γ(t),which was always used to describe the adsorption at air/solution interfaces,was derived.Two cases of adsorption,i.e. the short time limit and the long time limit,were mainly discussed.As an example,surfactant C_(12)E_7 was chosen and the equilibria and the dynamic surface tensions of its aqueous solution at 25 ℃ were measured.It was proved that for the short time limit the whole process was controlled only by diffusion,however,within the long time range a mixed diffusion-adsorption controlled process appeared.
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Received 2005-01-15; published 2005-01-15
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LIU Jun-ji, WANG Chuang-ye, XU Ling.Adsorption Kinetics of Surfactant at Air/Solution Interface[J]  Chemcial Industry and Engineering, 2005,V22(1): 4-7
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