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Chemcial Industry and Engineering 2007, Vol. 24 Issue (4) :373-377    DOI:
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Thermodynamic Analysis of Synthesis of Dimethyl-hexane-1,6-dicarbamate
SUN Da-lei,DENG Jian-ru(College of Chemical and Engineering,Hunan University,Changsha 410082,Hunan Province,China)
(College of Chemical and Engineering,Hunan University,Changsha 410082,Hunan Province,China

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Abstract The synthesis of dimethyl-hexane-1,6-dicarbamate(HDU) from 1,6-Hex anediamine and dimethyl carbonate is a complex reaction system.The reaction heat,change of gibbs free energy and equilibrium constant of the reactions are calculated by methods of group contribution.The comparison among the estimate data,literature data and experimental data shows that the results of estimation are reasonable,and very important for experimental research and scale up of the process.
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Received 2007-07-15; published 2007-07-15
Cite this article:   
SUN Da-lei,DENG Jian-ru.Thermodynamic Analysis of Synthesis of Dimethyl-hexane-1,6-dicarbamate[J]  Chemcial Industry and Engineering, 2007,V24(4): 373-377
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