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Chemcial Industry and Engineering 2018, Vol. 35 Issue (1) :34-38    DOI: 10.13353/j.issn.1004.9533.20161026
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Effects of Metal Components on the Adsorption Desulfurization Performance of Halloysite Nanotubes
Ma Zhi, Chen Hang, He Kangkang, Qi Xiaoye
Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

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Abstract 

The study was to investigate changes in the adsorption desulfurization performance of halloysite nanotubes(HNTs) with the introduction of metal components by incipient wetness impregnation. The samples were characterized by X-Ray diffractometer(XRD), adsorbed pyridine infrared spectroscopy(Py-IR) and N2-sorption. The experimental results showed that three kinds of metal components were mainly presented as their oxides on HNTs, and Co3O4, NiO and CuO can all improve the adsorption desulfurization performance of HNTs, and the desulfurization rate of HNTs with 10% NiO increased the most, from 30.10% to 47.51%. Metal oxides improved the amount of Lewis acid on the surface of HNTs, and the adsorption desulfurization performance of HNTs increased with the change of the amount of Lewis acid. Therefore, the amount of Lewis acid on the surface of HNTs is an important factor affecting the adsorption desulfurization performance of HNTs.

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Articles by authors
Ma Zhi
Chen Hang
He Kangkang
Qi Xiaoye
KeywordsHalloysite nanotubes;   metal components;   adsorption desulfurization     
Received 2016-03-15;
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Ma Zhi, Chen Hang, He Kangkang, Qi Xiaoye.Effects of Metal Components on the Adsorption Desulfurization Performance of Halloysite Nanotubes[J]  Chemcial Industry and Engineering, 2018,V35(1): 34-38
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