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Chemcial Industry and Engineering 2018, Vol. 35 Issue (1) :15-21    DOI: 10.13353/j.issn.1004.9533.20161095
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Conversion from Carbohydrate to 5-Hydroxymethylfurfural via the Fenton Reaction
Wu Yan1, Yang Zhenzhen1, Qi Wei1,2,3, Su Rongxin1,2,3, He Zhimin1,2
1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2. State Key Laboratory of Chemical Engineering, Tianjin 300072, China;
3. Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300072, China

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Abstract 

An efficient process for preparation of 5-hydroxymethylfurfural (5-HMF) from starch, glucose and fructose was developed via the Fenton reaction in water-butanol two-phase system. The influence factors of the reaction was investigated via the Fenton, including temperature, reaction time, the ratio of water to butanol, and the ratio of Fenton (Fe2+ and H2O2). The optimal conditions were obtained and the highest 5-HMF yields from starch, glucose and fructose were 46.5%,47.4% and 61.7%, respectively. Finally the mechanism of the Fenton reaction was discussed and found that Fenton could degrade starch to glucose, catalyze glucose to fructose and convert fructose to 5-HMF.

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Articles by authors
Wu Yan
Yang Zhenzhen
Qi Wei
Su Rongxin
He Zhimin
Keywordsstarch;   glucose;   fructose;   5-hydroxymethylfurfural;   Fenton;   catalyze     
Received 2016-05-09;
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Wu Yan, Yang Zhenzhen, Qi Wei, Su Rongxin, He Zhimin.Conversion from Carbohydrate to 5-Hydroxymethylfurfural via the Fenton Reaction[J]  Chemcial Industry and Engineering, 2018,V35(1): 15-21
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