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Chemcial Industry and Engineering 2015, Vol. 32 Issue (4) :7-12    DOI: 10.13353/j.issn.1004.9533.2015.04.002
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Synthesis and Spectra Properties of Perylene Diimide Derivatives
Hu Xiaoxia, Liu Dongzhi, Li Wei, Zhou Xueqin
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

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Abstract 

Two novel perylene diimides derivatives, N-(1-hexylheptyl)-N'-phenyl-perylene-3,4:9,10-tetracarboxydiimide and N-(1-hexylheptyl)-N'-phenyl-1,7-di(p-tert-butylphenoxy)-perylene-3,4:9,10-tetracarboxydiimide, were synthesized from 3,4:9,10-perylenetetracarboxylic dianhydride. The structures were characterized by 1H NMR and MS. The spectra properties were investigated through UV-Vis and fluorescence spectrum, the results showed that the introduction of electron-donating group at the bay area of perylene structure caused obvious bathochromic shift of maximal absorption and a big Stokes shift of 29 nm.

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Articles by authors
Hu Xiaoxia
Liu Dongzhi
Li Wei
Zhou Xueqin
Keywordsperylene diimide;   synthesis;   spectrum     
Received 2014-03-03;
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Hu Xiaoxia, Liu Dongzhi, Li Wei, Zhou Xueqin.Synthesis and Spectra Properties of Perylene Diimide Derivatives[J]  Chemcial Industry and Engineering, 2015,V32(4): 7-12
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