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Chemcial Industry and Engineering 2014, Vol. 31 Issue (1) :1-7    DOI: 10.13353/j.issn.1004.9533.2014.01.001
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Preparation of Ordered Mesoporous Carbon-Based Solid Acid Catalyst and Its Use for Synthesis of Bisphenol A
 SHAN  Wen-Bin, DONG  Xiu-Qin, ZHANG  Min-Hua
(1Research & Development Center for Petrochemical Technology, Tianjin University, Tianjin 300072, China;
2Key Laboratory of Green Synthesis and Conversion, Tianjin University, Tianjin 300072, China)

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Abstract The novel ordered mesoporous carbon-based solid acid catalyst, possessing highly ordered mesoporous channel structure, high density of —SO3H groups, was prepared by softtemplate method. The catalysts were characterized by N2 adsorptiondesorption, X-ray powder diffraction, transmission electron microscopy, EDX spectroscopy and acid-base titration. The effects of carbonization temperature on mesoporous porous structure, surface acidity and catalytic performance of mesoporous carbonbased solid acid catalysts were investigated. The experimental results showed that the optimal carbonization temperature was 500 ℃ and the mesoporous carbonbased solid acid catalyst carbonized under 500 ℃ contained highly ordered mesoporous channel structure and high acid density after sulfonation. The resulting catalyst was applied to the synthesis of bisphenol A from condensation of acetone with phenol and showed significantly higher activity than several solid acid catalysts(001×7, D072, Amorphous carbonbased solid acid). It can be clearly seen that the ordered mesoporous carbonbased solid sulfonic acid catalyst is a novel efficient solid acid catalyst and can be applied to the area of bisphenol A production.
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SHAN Wen-Bin
DONG Xiu-Qin
ZHANG Min-Hua
Keywordsordered mesoporous carbon   solid acid catalyst   carbonization   condensation   bisphenol A     
Received 2013-04-21;
Fund:

国家自然科学基金项目(21104035)。

Corresponding Authors: 张敏华,电话:(022)27406119; E-mail: mhzhang@tju.edu.cn。     Email: mhzhang@tju.edu.cn
About author: 山文斌(1988-),男,硕士研究生,从事应用催化方面的研究。
Cite this article:   
SHAN Wen-Bin, DONG Xiu-Qin, ZHANG Min-Hua.Preparation of Ordered Mesoporous Carbon-Based Solid Acid Catalyst and Its Use for Synthesis of Bisphenol A[J]  Chemcial Industry and Engineering, 2014,V31(1): 1-7
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