Synthesis and Evaluation of Sulfonated Polyacrylamide Based on Complex Initiation System
SONG Hua 1, 2 , WANG Zhong-Yuan1, DING Wei 1, WU Wen-Xiang 3, LI Feng1, 2
(1School of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318,China;
2Heilongjiang Provincial Key Laboratory of Chemical Engineering of Oil and Gas, Northeast Petroleum University, Daqing 163318,China;
3College of Petroleum Engineering, Northeast Petroleum University, Daqing 163318,China)
Abstract The copolymer (sulfonated polyacrylamide) of acrylamide (AM) and 2-acrylamide-2-methyl propane sulfonic acid (AMPS) were synthesized by using a complex initiation system which contains the redox initiator (ammonium persulfate and formaldehyde sulfoxylate sodium sulfite) and watersoluble azo initiator (azobisisobutylamidine hydrochloride). The effect of redox ratio, complex initiation ratio, reaction temperature, pH of the system, monomer concentration on the apparent viscosity of polymer solution were studied and the temperature tolerance and salt resistance were evaluated. The results showed that the SPAM had better temperature tolerance and salt resistance performance than industrial partially hydrolyzed polyacrylamide (HPAM 3.5×107).
SONG Hua 1, 2 , WANG Zhong-Yuan 1, DING Wei 1, WU Wen-Xiang 3, LI Feng 1, 2 .Synthesis and Evaluation of Sulfonated Polyacrylamide Based on Complex Initiation System[J] Chemcial Industry and Engineering, 2013,V30(5): 37-41