Preparation and Characterization of a Novel Catalyst RuB/ZnOZrO2 for Hydrogenation of Benzene to Cyclohexene
XIONG Jian-Ping1,2, WANG Bao-He1,2, ZHU Jing1,2, WANG Li-Li1,2
1.Research and Development Center of Petrochemical Technology, Tianjin University；2.Key Laboratory for Green Chemical Technology of the Ministry of Education,Tianjin University
Abstract Binary oxide supports with different Zn/Zr molar ratios were prepared, and the supports were characterized by XRD, TEM and N2 physisorption. XRD and TEM results showed that the ZnO-ZrO2 supports were nanosized. The physical properties of supports with different Zn/Zr ratios were almost the same. Ru-B/ZnO-ZrO2 catalysts were prepared by chemical reduction method, and characterized by XRD and DSC. The XRD and DSC results showed that the RuB/ZnO-ZrO2 catalyst consisted of an amorphous Ru-B alloy and of tetragonal ZrO2 crystallites. In the liquidphase selective hydrogenation of benzene to cyclohexene over the asprepared catalyst in the presence of 0.2 mol/L ZnSO4 at 140 ℃ under 4 MPa H2, a maximum cyclohexene yield of 43% was achieved.
XIONG Jian-Ping, WANG Bao-He, ZHU Jing, WANG Li-Li.Preparation and Characterization of a Novel Catalyst RuB/ZnOZrO2 for Hydrogenation of Benzene to Cyclohexene[J] Chemcial Industry and Engineering, 2013,V30(1): 20-26
2013, Vol. 30 
