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Chemcial Industry and Engineering 2012, Vol. 29 Issue (6) :1-6    DOI:
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Synthesis, Characterization and Catalytic Property in Oxidative  Carbonylation of Y-β Composite Zeolite
 WANG  Zeng-Zhu, HUANG  Shou-Ying, WANG  Sheng-Ping, MA  Xin-Bin
Key Lab for Green Chemical Technology of Ministry of Education, School of Chemical ; Engineering and Technology, Tianjin University

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Abstract Y-β composite zeolite was synthetized using preset crystal seeds method and characterized by FT-IR, SEM, BET and XRD. The characterization results indicated the Y-β composite zeolite had the structural feature of both Y and β zeolite instead of a mixture of them. The preparation conditions were investigated and it was found that crystallization time, SiO2/Al2O3 ratio and alkalinity could affect the ratio of Y and β in composite zeolite. In addition, the activity of the catalyst in oxidative carbonylation was investigated. The results revealed that Y-β composite zeolite prepared at crystallization time of 180 h, SiO2/Al2O3 ratio of 36, alkalinity of 1.8 showed relatively higher conversion of 1.3% and selectivity of 46.9%, in combination with the advantages of zeolite Y and β.
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Articles by authors
WANG Zeng-Zhu
HUANG Shou-Ying
WANG Sheng-Ping
MA Xin-Bin
KeywordsY-&beta   composite zeolite   synthesis   oxidative carbonylation   diethyl carbonate     
Received 2012-04-27;
Fund:

国家自然科学基金(20876112,20936003);高等学校博士学科点专项科研基金(20090032110021);高等学校学科创新引智计划(B06006)。

Corresponding Authors: 王胜平,电话:(022)87401818, E-mail:spwang@tju.edu.     Email: spwang@tju.edu.
About author: 王增竹(1987-),男,山东日照人,硕士研究生,研究方向为有机碳酸酯的合成。
Cite this article:   
WANG Zeng-Zhu, HUANG Shou-Ying, WANG Sheng-Ping, MA Xin-Bin.Synthesis, Characterization and Catalytic Property in Oxidative  Carbonylation of Y-β Composite Zeolite[J]  Chemcial Industry and Engineering, 2012,V29(6): 1-6
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