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Chemcial Industry and Engineering 1997, Vol. 14 Issue (4) :23-28    DOI:
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Separation of Binary Organic Mixture with Pervaporation Membrane
Huang Qian

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Abstract Homogeneous membrane of polyimide (PI) was employed in pervaporation to separate benzene—cyclohexane mixture. Flux rates and compositions of permeant liquid were measured. High selectivity for benzene has been found. Pervaporation flux depends upon the value of equilibrium solubility. The dependence of penetrant concentration in the membrane upon the diffusion coefficients may be expressed by an expoential equation under a certain limitation. Thus, we obtain plasticization factors r , which are compared with the calculated results of intercoordinate factors of bezene—PI membrane. We have found that Arrhenius equations is valid in expressing the relationship between temperature and K, flux rates, solubilities and diffusivities respectively.
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Keywordspervaporation benzene—cyclohexane polyimide     
Received 1997-10-15;
Cite this article:   
Huang Qian .Separation of Binary Organic Mixture with Pervaporation Membrane[J]  Chemcial Industry and Engineering, 1997,V14(4): 23-28
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