[an error occurred while processing this directive]
化学工业与工程
 首页 |  在线投稿 |  期刊介绍 |  编 委 会 |  投稿指南 |  期刊订阅 |  下载中心 |  出版伦理 |  联系我们 |  English
化学工业与工程 2001, Vol. 18 Issue (1) :1-7    DOI:
论文 最新目录 | 下期目录 | 过刊浏览 | 高级检索 << | >>
链状双苯基噁二唑基乙烯光化学性质的研究
庄俊鹏,王淑丽,郑艳,赵抒娜,张文勤
天津大学理学院!天津300072,天津大学理学院!天津300072,天津大学理学院!天津300072,天津大学理学院!天津300072,天津大学理学院!天津300072
Study on the Photochemical Properties of Chain Linked Bis(Phenyloxadiazoly)ethenes
ZHUANG Jun peng, WANG Shu li, ZHENG Yan, ZHAO Shu na, ZHANG Wen qin (School of Science, Tianjin University, Tianjin 300072, China)
(School of Science, Tianjin University, Tianjin 300072, China

摘要
参考文献
相关文章
Download: PDF (0KB)   HTML ()   Export: BibTeX or EndNote (RIS)      Supporting Info
摘要 本文合成了 1 ,n 双 [4 [2 [2 ( 5 苯基 1 ,3,4 二唑基 ) ]乙烯基 ]苯氧基 ]烷烃(n分别为 3,4,6 )和 2 ,2′ 双 [4 [2 [2 ( 5 苯基 1 ,3,4 二唑基 ) ]乙烯基 ]苯氧基 ]乙醚 4个未见文献报导的链状双杂芳基乙烯化合物及其参比物 4 [2 [2 ( 5 苯基 1 ,3,4 二唑基 ) ]乙烯基 ]苯甲醚。用元素分析、紫外、红外、核磁和质谱表征了化合物的结构并用紫外吸收光谱跟踪研究了其在稀溶液中的光化学性质。结果发现 :上述化合物在高压汞灯照射下可同时发生反顺异构化和 [2 + 2 ]分子内光二聚两种反应 ,前者迅速可逆 ,后者缓慢且不可逆。其分子内光二聚体在短波长紫外光照射下极易进行逆 [2 + 2 ]光解开环反应而得到原来的化合物。另外 ,上述化合物的分子内光二聚反应和光解开环反应可反复进行多次 ,再现性较好 ,此类化合物在光信息储存方面具有潜在应用前景
Service
把本文推荐给朋友
加入我的书架
加入引用管理器
Email Alert
RSS
作者相关文章
庄俊鹏
王淑丽
郑艳
赵抒娜
张文勤
关键词双杂芳基乙烯   分子内光二聚     
Abstract: n bis[trans 4 [2 [2 (5 pheny1 1,3,4 oxadiazoly)]etheny1]phenoxy]alkanes ( n =3,4,6),2,2′ bis[trans 4 [2 [2 (5 pheny1-1,3,4 oxadiazoly)]etheny1] phenoxy]ethy1 ether (D) and their model compound trans 4 [2 [2 (5 pheny1-1,3,4 oxadiazoly)]etheny1]anisole (E) were synthesized. Their structures were identified by elemental analysis, IR, UV, 1H NMR, 13 C NMR and MS. UV spectra were used to illustrate their photochemical properties under the irradiation of high pressure mercury lamp. It was found that A D undergo two kinds of reactions, the trans cis isomerization and (2+2) intramolecular photodimerization. The former is fast and reversible, but the later is slow and irreversible. The intramolecular photodimers of A D can photolysis easily under the irradiation of low pressure mercury lamp. Furthermore, The reversible reaction between the intramolecular photodimerization of A D and the photolysis of the formed dimers can undergo many times with high reproducibility which indicates that these sort of compounds have potential utilization in the field of photo info memory.
Keywords:   
Received 2001-01-15; published 2001-01-15
引用本文:   
庄俊鹏,王淑丽,郑艳,赵抒娜,张文勤.链状双苯基噁二唑基乙烯光化学性质的研究[J].  化学工业与工程, 2001,18(1): 1-7
ZHUANG Jun peng, WANG Shu li, ZHENG Yan, ZHAO Shu na, ZHANG Wen qin .Study on the Photochemical Properties of Chain Linked Bis(Phenyloxadiazoly)ethenes[J].  Chemcial Industry and Engineering, 2001,18(1): 1-7
Copyright 2010 by 化学工业与工程