Abstract��
The synthesis of dimethyl-hexane-1,6-dicarbamate(HDU) from 1,6-Hex anediamine and dimethyl carbonate is a complex reaction system.The reaction heat,change of gibbs free energy and equilibrium constant of the reactions are calculated by methods of group contribution.The comparison among the estimate data,literature data and experimental data shows that the results of estimation are reasonable,and very important for experimental research and scale up of the process.
SUN Da-lei,DENG Jian-ru.Thermodynamic Analysis of Synthesis of Dimethyl-hexane-1,6-dicarbamate[J]. Chemcial Industry and Engineering, 2007,24(4): 373-377
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