Preparation of W-Catalyst Supported on Montmorillonite
WANG Wei,LIU Ji-chun,ZHANG Yu-qing,LUO Jie (Key Lab of Polymer Science and Nanotechnology,Henan University of Science & Technology, Luoyang 471003,Henan Province,China)
(Key Lab of Polymer Science and Nanotechnology,Henan University of Science & Technology, Luoyang 471003,Henan Province,China
Abstract��
WCl_6/t-BuArOH complex compound was prepared,which makes WCl_6 dissolved well in organic solvent and more stable in air.Through exchange with ions or groups in the interlayer of montmorillonite(MMT),WCl_6/t-BuArOH complex compound can form an intercalative complex catalyst.Results from XRD,SEM and TEM indicated that organically modified MMT can act as a good carrier for the WCl_6/t-BuArOH complex compound,whereas the nonmodified inorganic MMT can not.
WANG Wei,LIU Ji-chun,ZHANG Yu-qing,LUO Jie .Preparation of W-Catalyst Supported on Montmorillonite[J]. Chemcial Industry and Engineering, 2007,24(5): 424-427