深海水下作业用稀土铝酸锶发光聚合物复合材料的研究进展

摘要稀土铝酸锶发光聚合物复合材料是目前应用最广泛的发光材料，可用于制备海洋用发光纤维，有望解决深海、黑暗条件的水下作业难题。主要综述了稀土铝酸锶在聚丙烯、聚乙烯、聚对苯二甲酸乙二醇酯、聚甲基丙烯酸甲酯和聚氨酯等聚合物中的研究进展，描述了稀土铝酸锶对聚合物复合材料物理力学性能和发光特性的影响，阐明了聚合物发光复合材料在水下作业领域的应用前景。

	Service

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	Email Alert
	RSS
	作者相关文章
	谢锏辉
	戚佩瑶
	胡绍峰
	王朋飞
	李昂
	刘晓非

关键词：稀土铝酸锶聚合物复合材料长余辉夜光纤维水下识别

Abstract： Rare earth strontium aluminate luminescent polymer composites are currently the most widely used luminescent materials. They can be used to make marine luminous fibers and are expected to solve the problems of underwater operations in deep sea and dark conditions. This article mainly reviews the research progress of rare earth strontium aluminate in polymers such as polypropylene, polyethylene, polyethylene terephthalate, polymethyl methacrylate and polyurethane, and describes the effect of rare earth strontium aluminate on polymerization. The influence of the physical and mechanical properties and luminescence characteristics of the polymer composite material clarifies the application prospects of the polymer luminescence composite material in the field of underwater operations.

Keywords： rare earth strontium aluminate； polymer composite； long afterglow； luminous fiber； underwater recognition

Received 2021-02-08;

Corresponding Authors: 刘晓非,教授,E-mail:liuxf315@qq.com。 Email: liuxf315@qq.com

About author: 谢锏辉(1987-),男,工程师,现从事海洋石油工程设计及施工技术方面的研究。

引用本文:

谢锏辉, 戚佩瑶, 胡绍峰, 王朋飞, 李昂, 刘晓非.深海水下作业用稀土铝酸锶发光聚合物复合材料的研究进展[J]. 化学工业与工程, 2022,39(2): 61-68

XIE Jianhui, QI Peiyao, HU Shaofeng, WANG Pengfei, LI Ang, LIU Xiaofei.Research progress of rare earth strontium aluminate luminescent polymer composites used in underwater operations[J]. Chemcial Industry and Engineering, 2022,39(2): 61-68

[1] MARTIÍN-RODRIÍGUEZ E, JAQUE D, SANZ-GARCIÍA J A, et al. Phase transition induced gain depression in Nd³⁺:SBN lasers[J]. Journal of Applied Physics, 2006, 100(11):113114-113118
[2] SURIYAMURTHY N, PANIGRAHI B S. Effects of non-stoichiometry and substitution on photoluminescence and afterglow luminescence of Sr₄Al₁₄O₂₅:Eu²⁺, Dy³⁺ phosphor[J]. Journal of Luminescence, 2008, 128(11):1809-1814
[3] SAKIRZANOVAS S, KATELNIKOVAS A, DUTCZAK D, et al. Synthesis and Sm²⁺/Sm³⁺ doping effects on photoluminescence properties of Sr₄Al₁₄O₂₅[J]. Journal of Luminescence, 2011, 131(11):2255-2262
[4] ZHENG R, XU L, QIN W, et al. Electrospinning preparation and photoluminescence properties of SrAl₂O₄:Ce³⁺ nanowires[J]. Journal of Materials Science, 2011, 46(23):7517-7524
[5] MIYAMOTO Y, KATO H, HONNA Y, et al. An orange-emitting, long-persistent phosphor, Ca₂Si₅N₈:Eu²⁺,Tm³⁺[J]. Journal of the Electrochemical Society, 2009, 156(9):J235-J241
[6] DORENBOS P. Mechanism of persistent luminescence in Eu²⁺ and Dy³⁺ codoped aluminate and silicate compounds[J]. Journal of the Electrochemical Society, 2005, 152(7):H107-H110
[7] BURNELL-JONES P. Luminescent gel coats and moldable resins:US6207077[P]. 2001-03-27
[8] TOH K, NAGATA S, TSUCHIYA B, et al. Luminescence characteristics of Sr₄Al₁₄O₂₅:Eu, Dy under proton irradiation[J]. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions With Materials and Atoms, 2006, 249(1/2):209-212
[9] MOLINA C, DAHMOUCHE K, SANTILLI C V, et al. Structure and luminescence of Eu³⁺-doped class I Siloxane-poly(ethylene glycol) hybrids[J]. Chemistry of Materials, 2001, 13(9):2818-2823
[10] BHAT S S, CERMELLI C A, LO K H. Polyester mooring for ultra-deepwater applications[C]//Proceedings of ASME 200221st International Conference on Offshore Mechanics and Arctic Engineering. Oslo, Norway,2009
[11] 黄维, 刘海笑. 新型深水系缆非线性动力特性研究进展[J]. 海洋工程, 2009, 27(4):140-144 HUANG Wei, LIU Haixiao. Research progress on dynamic nonlinear properties of new type deep-water mooring lines[J]. The Ocean Engineering, 2009, 27(4):140-144(in Chinese)
[12] 黄维, 刘海笑. 新型深水系泊系统非线性循环动力分析[J]. 海洋工程, 2010, 28(2):22-28, 36 HUANG Wei, LIU Haixiao. Cyclic nonlinear analysis of new-type deepwater mooring systems[J]. The Ocean Engineering, 2010, 28(2):22-28, 36(in Chinese)
[13] JI C, YUAN Z, CHEN M. Study on a new mooring system integrating catenary with taut mooring[J]. China Ocean Engineering, 2011, 25(3):427-440
[14] 连宇顺, 刘海笑, 黄维. 超深水混合缆绷紧式系泊系统非线性循环动力分析[J]. 海洋工程, 2013, 31(3):1-8 LIAN Yushun, LIU Haixiao, HUANG Wei. Cyclic nonlinear analysis of ultra-deepwater hybrid mooring systems[J]. The Ocean Engineering, 2013, 31(3):1-8(in Chinese)
[15] 连宇顺, 刘海笑. 深水系泊高强聚乙烯缆绳的蠕变及破断实验研究[J]. 海洋工程, 2016, 34(3):10-18 LIAN Yushun, LIU Haixiao. Creep and creep-rupture experimental investigations of HMPE ropes for deepwater moorings[J]. The Ocean Engineering, 2016, 34(3):10-18(in Chinese)
[16] 连宇顺. 合成纤维系缆的复杂力学性能及其对绷紧式系泊系统动力响应的影响[D]. 天津:天津大学,2015 LIAN Yushun. Complicated mechanical behavior of synthetic fiber mooring ropes and its effects on the dynamic response of the tautwire mooring system for deep water[D]. Tianjin:Tianjin University, 2015(in Chinese)
[17] 连宇顺, 刘海笑. 海洋系泊工程中合成纤维系缆研究述评[J]. 海洋工程, 2019, 37(1):142-154 LIAN Yushun, LIU Haixiao. Review of synthetic fiber ropes for deepwater moorings[J]. The Ocean Engineering, 2019, 37(1):142-154(in Chinese)
[18] 桑巍, 佟寅. 高模量合成纤维缆绳在海洋调查绞车上的应用[J]. 船舶, 2020, 31(6):1-8 SANG Wei, TONG Yin. Application of high modulus synthetic fiber ropes in oceanographic research winches[J]. Ship & Boat, 2020, 31(6):1-8(in Chinese)
[19] JANG S C, SHU Y, CHUANG F, et al. The dispersants effect on physical properties of long-lasting luminescent polypropylene[J]. Journal of Applied Polymer Science, 2012, 124(6):4645-4654
[20] 罗军, 高大海, 葛明桥, 等. 稀土硅酸镁锶聚丙烯夜光纤维的构相与余辉性能[J]. 纺织学报, 2013, 34(4):22-26 LUO Jun, GAO Dahai, GE Mingqiao, et al. Conformation and afterglow properties of rare earth magnesium strontium silicate polypropylene luminescent fiber[J]. Journal of Textile Research, 2013, 34(4):22-26(in Chinese)
[21] SHI C, HOU X, LI X, et al. Preparation and characterization of persistent luminescence of regenerated cellulose fiber[J]. Mater Sci, 2017, 28(1):1015-1021
[22] EBRAHIMZADE A, MOJTAHEDI M R M, SEMNANI R R. Study on characteristics and afterglow properties of luminous polypropylene/rare earth strontium aluminate fiber[J]. Journal of Materials Science:Materials in Electronics, 2017, 28(11):8167-8176
[23] 张思灯, 王兴平, 孙宾, 等. 聚丙烯纤维细旦、可染及功能化改性研究进展[J]. 高分子通报, 2013,(10):50-59 ZHANG Sideng, WANG Xingping, SUN Bin, et al. Research progress in fine denier, dyeable and functional polypropylene fibers[J]. Polymer Bulletin, 2013,(10):50-59(in Chinese)
[24] YAM R C M, MAK D M T. A cleaner production of rice husk-blended polypropylene eco-composite by gas-assisted injection moulding[J]. Journal of Cleaner Production, 2014, 67:277-284
[25] THAKUR V K, VENNERBERG D, KESSLER M R. Green aqueous surface modification of polypropylene for novel polymer nanocomposites[J]. ACS Applied Materials & Interfaces, 2014, 6(12):9349-9356
[26] YU Y, WANG J, ZHU Y N, et al. Researches on preparation and properties of polypropylene nonwovens containing rare earth luminous materials[J]. Journal of Rare Earths, 2014, 32(12):1196-1200
[27] HARANATH D, SHANKER V, CHANDER H, et al. Tuning of emission colours in strontium aluminate long persisting phosphor[J]. Journal of Physics D:Applied Physics, 2003, 36(18):2244-2248
[28] NAG A, KUTTY T R N. Role of B₂O₃ on the phase stability and long phosphorescence of SrAl₂O₄:Eu, Dy[J]. Journal of Alloys and Compounds, 2003, 354(1/2):221-231
[29] PENG M, PEI Z, HONG G, et al. Study on the reduction of Eu³⁺→Eu²⁺ in Sr₄Al₁₄O₂₅:Eu prepared in air atmosphere[J]. Chemical Physics Letters, 2003, 371(1/2):1-6
[30] HÖLSÄ J, JUNGNER H, LASTUSAARI M, et al. Persistent luminescence of Eu²⁺ doped alkaline earth aluminates, MAl₂O₄:Eu²⁺[J]. Journal of Alloys and Compounds, 2001, 323/324:326-330
[31] YEN W, SHIONOYA S, YAMAMOTO H. Practical applications of phosphors[M]. London:CRC Press, 2006
[32] BEM D B, LUYT A S, DEJENE F B, et al. Structural, luminescent and thermal properties of blue SrAl₂O₄:Eu²⁺, Dy³⁺ phosphor filled low-density polyethylene composites[J]. Physica B:Condensed Matter, 2009, 404(22):4504-4508
[33] POGREB R, POPOV O, LIRTSMAN V, et al. Luminescent properties of PP and LDPE films and rods doped with the Eu(Ⅲ)-La(Ⅲ) complex[J]. Polymers for Advanced Technologies, 2006, 17(1):20-25
[34] 郑峰, 苏佳祥, 宋剑斌, 等. 马来酸酐接枝聚乙烯对稀土荧光竹塑复合材料性能的影响[J]. 材料导报, 2015, 29(20):38-42 ZHENG Feng, SU Jiaxiang, SONG Jianbin, et al. Effects of PE-g-MAH on the properties of rare earth fluorescent bamboo plastic composites[J]. Materials Review, 2015, 29(20):38-42(in Chinese)
[35] GE M, GUO X, YAN Y. Preparation and study on the structure and properties of rare-earth luminescent fiber[J]. Textile Research Journal, 2012, 82(7):677-684
[36] YAN Y, GE M, LI Y, et al. Morphology and spectral characteristics of a luminous fiber containing a rare earth strontium aluminate[J]. Textile Research Journal, 2012, 82(17):1819-1826
[37] ZHANG J, GE M. A study of an anti-counterfeiting fiber with spectral fingerprint characteristics[J]. The Journal of the Textile Institute, 2011, 102(9):767-773
[38] ZHANG J, GE M. Effect of polymer matrix on the spectral characteristics of spectrum-fingerprint anti-counterfeiting fiber[J]. The Journal of the Textile Institute, 2012, 103(2):193-199
[39] ZHANG J, GE M. Effects of transparent inorganic pigment on spectral properties of spectrum-fingerprint anti-counterfeiting fiber containing rare earths[J]. Journal of Rare Earths, 2012, 30(9):952-957
[40] SHI C, HOU X, LI X, et al. Preparation and characterization of persistent luminescence of regenerated cellulose fiber[J]. Journal of Materials Science:Materials in Electronics, 2017, 28(1):1015-1021
[41] MISHRA S B, MISHRA A K, REVAPRASADU N, et al. Strontium aluminate/polymer composites:Morphology, luminescent properties, and durability[J]. Journal of Applied Polymer Science, 2009, 112(6):3347-3354
[42] ZHU Y, GE M. Effect of y/x ratio on luminescence properties of xSrO·yAl₂O₃:Eu²⁺, Dy³⁺ luminous fiber[J]. Journal of Rare Earths, 2014, 32(7):598-602
[43] ZHU Y, GE M. Effect of light conversion agent on the luminous properties of rare earth strontium aluminate luminous fiber[J]. Journal of Materials Science:Materials in Electronics, 2016, 27(1):580-586
[44] ZHU Y, GE M, CHEN Z. Preparation and properties of rare earth luminous fiber containing red organic fluorescent pigment[J]. Journal of Rare Earths, 2013, 31(11):1043-1048
[45] PENG L, LUO Y, DAN Y, et al. The study of preparation and luminescence of polymethyl methacrylate/rare earth composite luminescent materials[J]. Colloid and Polymer Science, 2006, 285(2):153-160
[46] 樊永伟, 孙启龙, 刘国军, 等. 可涂覆于鹅卵石表面的水性发光涂料的性能[J]. 化学工程与装备, 2015(4):1-3 FAN Yongwei, SUN Qilong, LIU Guojun, et al. Performance of water-based luminescent paint that can be applied to the surface of cobblestone[J]. Chemical Engineering & Equipment, 2015(4):1-3(in Chinese)
[47] 王可, 马倩, 王曙东, 等. 荧光防水透湿特种防护面料的开发[J]. 纺织导报, 2015(5):77-78 WANG Ke, MA Qian, WANG Shudong, et al. Development of laminated protective fabric with fluorescent water-proof and moisture-permeable properties[J]. China Textile Leader, 2015(5):77-78(in Chinese)
[48] 陈湘南. 蓄光涂料及其开发动向[J]. 中国涂料, 2000, 15(6):35-38 CHEN Xiangnan. Light-storing coatings and its development trend[J]. China Paint, 2000, 15(6):35-38(in Chinese)
[49] 段海婷. 铝酸锶:铕镝发光粉的制备及其在水性聚氨酯涂料中的应用研究[D]. 湖南株洲:湖南工业大学, 2009 DUAN Haiting. Studies on the preparation of strontium aluminates:europium dysprosium phosphors powder and applicates in waterborne polyurethane paint[D]. Hunan Zhuzhou:Hunan University of Technology, 2009(in Chinese)