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化学工业与工程
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��ѧ��ҵ�빤�� 2011, Vol. 28 Issue (2) :59-62    DOI:
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MoP/SiO2-TiO 2-ZrO 2�����ļ����ѷ������Ż�
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1������ʯ�ͻ�����ѧʯ�ͻ���ѧԺ������ ��˳ 113001�� 2����˳ְҵ����ѧԺ������ ��˳ 113001
Optimization of Hydrodearomatization to Naphthalene with  MoP/SiO2-TiO2-ZrO2 Catalyst
YANG Xin��jia1, DING Bao��hong 2, LU Meng��meng1, ZANG Shu��liang1
1��School of Petrochemical Technology, Liaoning Shihua University, Fushun 113001, China;
 2�� Fushun Vocational Technical College, Fushun 113001, China

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�ؼ����� MoP/SiO2-TiO2-ZrO2�߻���   ��   �����ѷ�   ��������     
Abstract�� In this paper, SiO2-TiO2-ZrO2 composite carrier was prepared by coprecipitation method and  was used as supports for preparing MoP/SiO2-TiO2-ZrO2 catalyst. In a fixed��bed microreactor, with the naphthalene and dodecane solution as  model compound,  the effects of the four factors of reaction temperature, reaction pressure, liquid hourly space velocity and  volume ratio of hydrogen to oil on the dearomatization  were investigated by  orthogonal test. The optimized process conditions of hydrodearomatization were obtained as: reaction temperature of 360 �棬reaction pressure of 5 MPa, LHSV(liquid hourly space velocity) of 3 h-1  and  volume ratio of hydrogen to oil 400��1, the conversion rate of naphthalene was 91.23%. Under this reaction condition, the cetane number of FCC diesel oil can increase more than 15 unites, and the yield reaches  96.28%.
Keywords�� MoP/SiO2��TiO2��ZrO2 catalyst   naphthalene   hydrodearomatization   orthogonal experiments     
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������, ������, ·����, �����.MoP/SiO2-TiO 2-ZrO 2�����ļ����ѷ������Ż�[J].  ��ѧ��ҵ�빤��, 2011,28(2): 59-62
YANG Xin-Jia, DING Bao-Hong, LU Meng-Meng, ZANG Shu-Liang.Optimization of Hydrodearomatization to Naphthalene with  MoP/SiO2-TiO2-ZrO2 Catalyst[J].  Chemcial Industry and Engineering, 2011,28(2): 59-62
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