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��ѧ��ҵ�빤�� 1999, Vol. 16 Issue (5) :270-274    DOI:
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Kinetice Study of Brom ide Oxidation on the Anode Electrode in Alkaline Solution
Wu Ailian Sun Yanping
( Departm ent of Chem ical Engineering, Taiyuan University of technology, Taiyuan 030024

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Abstract�� Kinetic m odelw as presented for Br- oxidation on the anode electrode in alka line solution taking account ofthe side reactions and by theoretically analyzing theeffection of brom ine com plexing��hydrolysis equilibrium ofbrom ide and dissociationofhypobrom ous acid on the anode reactions. The reaction characteristic of Br- at arotating disk electrode w as abtained by stationary polarization and transient cyclicvoltam m etry. The m ain process at electrode reactions is Br- oxidation into Br2 byanalysis of the cyclic voltage current. The kinetic param eters w ere obtained by ap plying the m ethod ofnonlineer regressin. The expected results by the m odelare incorrespondence w ith the experim entaldata.
Keywords�� Br- oxidation   electrode reaction   kinetics   rotating disk electrode   alka line solution     
Received 1999-09-15; published 1999-09-15
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�䰮��,����ƽ.������Һ��������������������ѧ���о�[J].  ��ѧ��ҵ�빤��, 1999,16(5): 270-274
Wu Ailian Sun Yanping.Kinetice Study of Brom ide Oxidation on the Anode Electrode in Alkaline Solution[J].  Chemcial Industry and Engineering, 1999,16(5): 270-274
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