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化学工业与工程 2005, Vol. 22 Issue (4) :267-270    DOI:
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固化温度对苯甲基化木材制备的聚氨酯树脂微相分离的影响
付贤树,程发,李厚萍,魏玉萍
天津大学理学院,天津大学理学院,天津大学理学院,天津大学理学院 天津300072 ,天津300072 ,天津300072 ,天津300072
Effect of Solidifying Temperature on Microsphase Separation of Benzylated Wood Based Polyurethane
FU Xian-shu, CHENG Fa, LI Hou-ping, WEI Yu-ping(School of Sciences, Tianjin University, Tianjin 300072, China)
(School of Sciences, Tianjin University, Tianjin 300072, China

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摘要 以二价酸酯DBE(己二酸、戊二酸、丁二酸的混合酯)与乙酸丁酯(质量比5∶1)的混合溶剂为液化试剂的苯甲基化木材溶液与甲苯二异氰酸酯 三羟甲基丙烷(TDI TMP)的预聚物为固化剂进行反应制备了聚氨酯树脂。利用FT IR、DSC、WXRD、DTA及TG等测试手段,研究了固化温度对聚氨酯树脂的微相分离和热性能的影响。结果表明,高温固化样品的微相分离程度较小,树脂的硬段初始分解温度有所降低,但软段的初始分解温度则有所提高。
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付贤树
程发
李厚萍
魏玉萍
关键词聚氨酯   微相分离   氢键   硬段微区     
Abstract: A series of polyurethane resin samples were synthesized by benzylated wood solution using DBE (dimethyl esters of adipic, glutaric, and succinic acids) and n-butyl acetate as solvent and the adduct of toluene diisocyanate (TDI)/trihydroxymethyl (TMP) propane. FT-IR,WXRD,DTA,TG and DSC are used to analyze the effect of solidifying temperature on microsphase separation and thermal property of the resins. Results show that with the solidifying temperature increasing, the degree of microsphase separation is reduced, the decomposed temperature of hard segment is decreased and the decomposed temperature of soft segment is increased.
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Received 2005-07-15; published 2005-07-15
引用本文:   
付贤树,程发,李厚萍,魏玉萍.固化温度对苯甲基化木材制备的聚氨酯树脂微相分离的影响[J].  化学工业与工程, 2005,22(4): 267-270
FU Xian-shu, CHENG Fa, LI Hou-ping, WEI Yu-ping.Effect of Solidifying Temperature on Microsphase Separation of Benzylated Wood Based Polyurethane[J].  Chemcial Industry and Engineering, 2005,22(4): 267-270
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