��Ag(bbte)BF_4�ĺϳ��뾧��ṹ

ժҪ ��AgBF4��1,2-˫��(bbte)Ϊԭ��,�ϳ��һ��Ag(bbte)BF4��,��Ԫ�ط��ױ��X-��ߵ��ⶨ��X��ߵ��ʾ��[Ag(bbte)BF4]n��Ag(I)��ƽ��λ��,bbte��Sԭ��һ��Ag(I),��һ��Sԭ��ڵ��Ag(I)��γ�һά��״�ṹ��λ�ۺ��б��ϵ,P2(1)/c�ռ�Ⱥ,��Ϊ:a=0.932(1)nm,b=0.799(1)nm,c=2.181(1)nm,��=97.671(9)��,��V=1.610 8(14)nm3,��ڷ��Z=4,��ܶ�dc=1.654 Mg/m3,��ϵ��=1.531 mm-1,(000)��ṹ��F(000)=808,�в��R1=0.069 1,wR2=0.137 8��

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Abstract�� A one-dimensional silver(I) complex,Ag(bbte)BF_4,has been formed from AgBF_4 and 1,2-bis(n-butylsulfanyl)ethane(bbte,C_(10)H_(22)S_2).The complex was characterized by elemental analysis and IR spectroscopy.The X-ray structure of Ag(bbte)BF_4 is a chain coordinative polymer involving trigonal [(��_2-S)_2,S] ligation with one S-donor bridging two adjacent Ag(I) centers while the other S-donor of the bbte ligand is non-bridging.The crystal belongs to monoclinic crystal system and P2(1)/c space group.Crystallographic data:a=0.932(1) nm,b=0.799(1) nm,c=2.181(1) nm,��=97.671(9)��,V=(1.610 8)(14) nm~3,Z=4,(d_c=)1.654 Mg/m~3,��=1.531 mm~(-1),F_((000))=808,R_1=(0.069 1),wR_2=(0.137 8).

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Received 2006-03-15; published 2006-03-15

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��Ρ;л��;�κ��;��;.��Ag(bbte)BF_4�ĺϳ��뾧��ṹ[J]. ��ѧ��ҵ�빤��, 2006,23(2): 126-129

CHEN Wei~1,XIE Chuang~1,SONG Hai-bin~2,WANG Jing-kang~1.Synthesis and Crystal Structure of a One-Dimensional Complex of Ag(bbte)BF_4[J]. Chemcial Industry and Engineering, 2006,23(2): 126-129

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