化学氧化法处理抗生素制药废水

摘要应用传统生化法处理抗生素制药废水,出水很难达到行业排放标准。采用光催化氧化法和氯氧化法对抗生素制药废水进行了研究,探讨了上述过程中光照时间、通气条件、初始pH值及投加有效氯量等因素对抗生素制药废水处理效果的影响。试验结果表明,这两种化学氧化法都能够有效地去除抗生素制药废水中的有机物,出水COD值达到《污水综合排放标准》(GB8978-1996)的二级标准。

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	顾俊璟
	王志
	樊智锋
	解利昕
	刘广春
	王世昌

关键词：制药废水抗生素化学氧化光催化氧化氯氧化

Abstract： The effluent of pharmaceutical wastewater containing antibiotic by conventional biological treatments is hard to reach the industry discharge standard.The treatment of pharmaceutical wastewater containing antibiotic was performed by both photocatalysis oxidation and chlorine oxidation.The effects of the parameters during these processes,such as irradiation time,aerating condition,initial pH value and chlorine dosage,were investigated.Experimental results indicated that both of the chemical oxidation methods can remove organic substance effectively and the effluent COD could reach the Ⅱ-class criteria specified in Integrated Wastewater Discharge Standard(GB8978-1996).

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Received 2007-07-15; published 2007-07-15

引用本文:

顾俊璟;王志;樊智锋;解利昕;刘广春;王世昌;.化学氧化法处理抗生素制药废水[J]. 化学工业与工程, 2007,24(4): 291-294

GU Jun-jing,WANG Zhi,FAN Zhi-feng,XIE Li-xin,LIU Guang-chun,WANG Shi-chang.Chemical Oxidation Technology in Treatment of Pharmaceutical Wastewater Containing Antibiotic[J]. Chemcial Industry and Engineering, 2007,24(4): 291-294

[1]	李宝东,刘冬梅,林涛.水处理过程中的化学氧化技术[J].哈尔滨商业大学学报(自然科学版),2004,20(2):199-202.
[2]	李勇华.化学氧化技术在废水处理过程中的应用与发展[J].舰船防化,2005,2:1-6.
[3]	北京水环境技术与设备研究中心,北京市环境保护科学研究院,国家城市环境污染控制工程技术研究中心.三废处理工程技术手册[M].北京:化学工业出版社,2000.
[4]	TUSNELDA E,FRITZ H.Removal of selected persistentorganic pollutants by heterogeneous photocatalysis in water[J].Catalysis today,2005,101:195-202.
[5]	HACHEM C,BOCQUILLON F,ZAHRAA O.Decolourization of textile industry wastewater by thephotocatalytic degradation process[J].Dyes and Pigments.2001,49:117-125
[6]	ANDREOZZI R,CANTERINO M,MAROTTA R.Antibiotic removal from wastewaters:The ozonation ofamoxicillin[J].Journal of Hazardous Materials.2005,122(3):243-250
[7]	AKMEHMET B,MERIH O.Treatment of pharmaceuticalwastewater containing antibiotics by O3and O3/H2O2processes[J].Chemosphere.2003,50(1):85-95
[8]	ARSLAN I,BALCIOGLU I.Biodegradability assessment ofozonated raw and biotreated pharmaceutical wastewater[J].Archives of Environmental Contamination and Toxicology.2002,43(4):425-431
[9]	蔡闽.次氯酸钙法处理发泡剂生产废水[J].化工环保,2004,24(6):440-443.
[10]	方华,吕锡武,贺启环.催化二氧化氯氧化处理难降解废水特性研究[J].工业给排水,2005,31(4):49-53.
[11]	张东翔,陆英梅,梨汉生.生物制药废水光催化氧化特性研究[J].环境保护,2004,12:25-28.
[12]	ROBERTO A,VINCENZO C,AMEDEO I.Advancedoxidation processes(AOP)for water purification andrecovery[J].Catalysis Today,1999,53:51-59.
[13]	赵朝成,张英,赵东风.超声/臭氧氧化处理含酚废水实验研究[J].油气田环境保护,2001,11(3):26-29.
[14]	熊辉,杨晓利,李光兴.次氯酸钠氧化脱除黄磷尾气中的硫、磷杂质[J].化工环保,2002,22(3):161-164.