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Abstract�� This paper systematically introduced the effect of the presence of small amounts of the third phase which may be solid particles or the second dispersed liquid phase(organic phase) on gas-liquid mass transfer processes.In different gas-liquid reactors(stirred reactor\bubble column reactor),with the joining of the third phase and the second despersed liquided,the coefficient of mass transfer,the rate of mass transfer and interface areas have been affected.Furthermore,the mechanism of gas-liquid mass transfer was reviewed and the further developments were predicted.

Keywords��

Received 2007-11-15; published 2007-11-15

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��;��ӱ;��;��;��;��̍;.��ļ��Һ��ʹ��̵�Ӱ��[J]. ��ѧ��ҵ�빤��, 2007,24(6): 536-544

LI Wen-xiu~1,BI Ying~1,YU San-san~1,JI Zhi-ling~1,YANG Lihong~1,WANG Xiao~2.Effect of Addition of the Thrid Phase on Gas-Liquid Mass Transfer[J]. Chemcial Industry and Engineering, 2007,24(6): 536-544

[1]	BEENACKERS A A C M,VAN SWAAIJ W P M.Masstransfer in gas-liquid slurry reactors[J].Chem Eng Sci,1993,48:3 109-3 139.
[2]	��,��.��Ϲ��΢��ǿ��Һ��о�[D].��:��ѧ,2004.
[3]	��֮,��,ë��ɰ.��ʽ��-Һ-Һ��Ӧ��ɢ�ʹ��[J].ʯ��뻯��,2000,31(10):54-59.
[4]	��,��ӧ,��.��ҺҺ��ϵ�Ķ�ά�Ǿ��ഫ��ģ��[C].��:�ڰ˽�ȫ��ѧ��ı��ļ�,1996.
[5]	�ɺ�.��ϸ��ǿ��Һ��ഫ�ʵĻ��о�[D].��:��ѧ,1997.
[6]	GOMEZPLATA A,REGAN T M.Mass transfer[J].IndEng Chem,1970,62(12):17-26.
[7]	��͢��,��.��ϳ��ȡ��ɹ��о�[J].�Ĵ��ѧѧ��:��̿�ѧ��,2002,34(5):102-105.
[8]	��,��ݰ.��-Һ-Һ��䷴Ӧ��ȡ�Ʊ��Ĺ��[J].��ѧ��,2003,54(11):1 654-1 657.
[9]	JOOSTEN G E H,SCHILDER J G M,JANSSEN J.Theinfluence of suspended solid material on the gas-liquid masstransfer in stirred gas-liquid contactors[J].ChemicalEngineering Science,1977,32(5):563-566.
[10]	NIENOW A M,KONE M,BUJUSKI W.Studies on thethree-phase mixing:A review and recent results[J].ChemEng Res Des,1986,64(1):35-42.
[11]	SCHMITZ M,STEIFF A.Gas/liquid interfacial area per unit10 and 10tric mass transfer coefficient in stirredslurry reactors[J].Chem Eng Tech.1987,10(3):204-215
[12]	HAMBY N,EDWARDS M F,NIENOW A W.��ҵ�еĻ�Ϲ��[M].��,��.��:�й�ʯ��,1991.
[13]	��,��ɲ�,�´��.��-Һ-��Һ��ܵ��о�[J].��ѧ��ҵ�빤��,1997,14(2):17-22,38.
[14]	SHARMA M M.Perspectives in gas-liquid reactions[J].Chem Engng Sci.1983,38(5):21-
[15]	ALPER E,OZTIIRK S.The effect of activated carbonloading on oxygen absorption into aqueous sodium sulphidesolutions in a slurry reactor[J].Chem Engng J(Lausanne.1986,32(2):127-130
[16]	��.��ѭ��е��Һ��ʹ��ϵ��[J].��ұ��,2000,21(4):10.
[17]	KARS R L,BEST R J,DRINKENBURG A A H.Theadsorption of propane in slurries of active carbon in water[J].Chemical Engineering Journal,1979,17(3):201-210.
[18]	ALPER E,DECKWER W D.Comments on gas absorptionwith catalytic reaction[J].Chemical Engineering Science.1981,36:1-
[19]	SCHMITZ M,STEIFF A,WEINSPACH P M.Gas-liquidinterfacial area per unit volume and volumetric mass transfercoefficient in stirred slurry reactors[J].Chem EngngTechnol,1987,10(3):204-215.
[20]	��.��ϵ��ϸ��ǿ��Һ��о�[D].��:��ѧ,2003.
[21]	�ɺ�.��ϸ��ǿ��Һ��ഫ��(��)��[J].��ѧ��,1999,50(6):12.
[22]	LI Yiao-ping.Gas-liquid mass transfer in multiphasemechanically stirred airlift reactor[J].Journal of NanjingUniversity of Chemical Technology,1998,20(3):51-55.
[23]	MILLS D B,RAPHAEL B,KIIRWAN D J.Effect of solidson oxygen transfer in agitated three-phase system[J].AIChE Journal.1987,33(9):1-
[24]	�º�ѫ.��ϸ̼��Һ��෴Ӧ��о�[D].��:�ӱ��ҵ��ѧ,2000.
[25]	SADA E.Gas holdup and mass transfer characteristics in athree phase bubble column[J].Industrial&EngineeringChemistry Process Design and Development.1986,25(2):472-476
[26]	GODBOLE S P,SCHUMPE A,SHAH Y H.Effect of solidwettability on gas-liquid mass transfer in a slurry bubblecolumn[J].Chemical Engineering Science,1990,45(12):3 593-3 595.
[27]	��绪,��.��е��跴Ӧ��Һ��[J].��ѧ��,2005,56(2):220-226.
[28]	WIMMERS O J,FORTUIN J M H.The use of adhesion ofcatalyst particles to gas bubbles to achieve enhancement ofgas absorption in slurry reactors��.Investigation ofparticle-to-bubble adhesion using the bubble pick-up method[J]..Chemical Engineering Science.1988,43(2):303-312
[29]	PANDIT A B,JOSHI J B.Mass and heat transfercharacteristics of three phase sparged reactors[J].ChemicalEngineering Research&Design.1986,64(2):125-157
[30]	NAGARAJ N,GRAY D J.Interfacial area and coalescencefrequency in gas-slurry stirred reactors[J].AIChE Journal.1987,33(9):1-
[31]	QUICKER G,ALPER E,DECKWER W D.Effect of fineactivated carbon particles on the rate of CO2absorption[J].AIChE Journal.1987,33(5):871-875
[32]	MEHRA A.Gas absorption in slurries of finite-capacitymicrophases[J].Chem Eng Sci.1990,45:1-
[33]	Van der MEER A B,BEENACKERS A A C M,BURGHARD R,et al.Gas/liquid mass transfer in a four-phase stirred fermentor:Effects of organic phase hold-upand surfactant concentration[J].Chem Eng Sci,1992,47:2 369-2 374.
[34]	�ֳ�,��,��.��ϸ��ǿ��Һ��ഫ��(��)ʵ��[J].��ѧ��,1999,50(4):469-476.
[35]	�ֳ�,��,��,��.��ɢ�ڶ�Һ��ǿ��Һ��ʵ�Ӱ��[J].��ѧ��,2000,28(2):23-33.
[36]	BRUINING W J,JOOSTEN G E H,BEENACKER A A CM,et al.Enhancement of gas-liquid mass transfer by adispersed second liquid phase[J].Chem Eng Sci.1986,41:1-
[37]	BRUINING W J,JOOSTEN G E H,BEENACKERS A A CM,et al.Enhancement of gas-liquid mass transfer by adisperse second liquid phase[J].Chem Eng Sci.1986,41(7):1-
[38]	CENTS A H G,BRILMAN D W F,VERSTEEG G F.Gasabsorption in an agitate gas-liquid-liquid system[J].ChemEng Sci,2001,56:1 075-1 083.
[39]	DECKWER W D,NGUYEN-TIEN K,KELKAR B G.Applicability of axial dispersion model to analyze masstransfer measurements in bubble columns[J].AIChEJournal,1983,6(29):915-921.
[40]	��֮,��,ë��ɰ.��ʽ��-Һ-Һ��Ӧ��ɢ�ʹ��[J].ʯ��뻯��,2000,31(10):54-59.
[41]	HASSAN I T M,ROBINSON C W.Oxygen transfer inmechanically agitated systems containing dispersedhydrocarbon[J].Biotechnol Bioeng.1977,19:661-682
[42]	JANAKIRMAN B,SHARMA M M.Solid-liquid and liquid-liquid slow and fast reaction[J].Chem Engng Sci.1985,40:235-245
[43]	JUNKER B H,HATTON T A,WANG D I C.Oxygentransfer enhancement in aqueous/per-fluorocarbonfermentation systems��.Experimental observations[J]..Biotechnol Bioengng.1990,35:578-591
[44]	ROLS J L,CONDORET J S,FONADE C.Modeling ofoxygen transfer in water through emulsified organic liquids[J].Chem Engng Sci.1991,46:1-
[45]	DUMONT E,DELMAS H.Mass transfer enhancement ofgas absorption in oil-in-water systems:A review[J].ChemEng Pro,2003,42:419-438.
[46]	ALPER E,DECKWER W D.Some aspects of gasabsorption mechanism in slurry reactors[J].NATO ASISeries E,1983,73(2):199-224.
[47]	YOSHIDA F,YAMANE T,MIYAMOTO Y.Oxygenabsorption into oil-in-water emulsions[J].Industrial andEngineering Chemistry:Process Design and Development.1970,9:570-577
[48]	LITTLE R J,VERSTEEG G F,Van SWAAIJ W P M.Physical absorption of CO2and propene into toluene/wateremulsions[J].AIChE Journal.1994,40:1-
[49]	ROLS J L,CONDORET J S,FONADE C,et al.Mechanism of enhanced oxygen transfer in fermentationusing emulsified oxygen-vectors[J].Biotechnology andBioengineering.1990,35:427-435
[50]	Van EDE C J,van HOUTEN R,BEENACKERS A A C M.Enhancement of gas to water mass transfer rates by adispersed organic phase[J].Chem Engng Sci,1995,50:2 911-2 930.
[51]	DAS T R,BANDOPADHYAY A,PARTHASARATHY R,et al.Gas-liquid interfacial area in stirred vessels:Theeffect of an immiscible liquid phase[J].Chem Eng Sci.1985,40(2):209-214
[52]	LINEK V,BENES P.A study of the mechanism of gasabsorption into oil-water emulsions[J].Chem Eng Sci.1976,31(11):1-
[53]	MEHRA V D,SHARMA M M.Mass transfer inmechanically agitated gas-liquid contactors[J].Chem EngSci.1971,26:461-479
[54]	ROLS J L,CONDORET J S,FONADE C,et al.Mechanism of enhanced oxygen transfer in fermentationusing emulsified oxygen-vectors[J].Biotechnol Bioeng.1990,35:427-435
[55]	SHARMA M M,MASHELKAR R A.Absorption withreaction in bubble columns[J].Chem E Symp Series,1968,28:10-21.
[56]	��Ǿ�.��̬��ȡ��ѧ��Ӱ��о�[D].��:��ѧ,2005.
[57]	KOIDE K.Gas holdup and 17tric liquid-phase masstransfer coefficient in solid-suspended bubble columns[J].Journal of Chemical Engineering of Japan.1984,17(5):459-466
[58]	JU L K,LEE J F,ARMIGER W B.Enhancing oxygentransfer in bioreactors by perfluorocarbon emulsions[J].Biotechnology Progress,1991,37:505.
[59]	��ѹ�,��,�ɺ�,��.4�ֱ��Լ��CO2��չ��̽��Ũ��Ӱ��о�[J].��ѧ��,1999,50(6):776.
[60]	DAS T R,BANDOPADHYAY A,PARTHASARAT R,etal.Gas-liquid interfacial area in stirred vessels:The effectof an immiscible liquid phase[J].Chem Eng Sci.1985,40(2):209-214
[61]	DAVIES J T.Turbulence Phenomena[M].New York:Accademic Press,1972.
[62]	LIN C,ZHOU M,XU C J.Axisymmetrical two-dimensionalheterogeneous mass transfer model for the absorption of gasinto liquid-liquid dispersions[J].Chemical EngineeringScience.1999,54(3):389-399
[63]	RAMCHANDRAN C A,SHARMA M M.Adsorption withfast reaction in a slurry containing sparingly soluble fineparticles[J].Chemical Engineering Science.1969,24:1-
[64]	YAGI H,HIKITA H.Gas absorption into a slurryaccompanied by chemical reaction with solute from sparinglysoluble particles[J].Chem Ertgrt,1987,36(3):169-174.
[65]	KARVE S,JUVEKAR V A.Gas absorption into slurriescontaining fine catalyst particles[J].Chemical EngineeringScience.1990,45(3):587-596
[66]	HOLSTVOOGD R D,van SWAAIJ W P M,vanDIERENDONCK L.The absorption of gases in aqueousactivated carbon slurries enhanced by adsorbing or catalyticparticles[J].Chemical Engineering Science,1988,43(8):2 181-2 187.
[67]	VINKE H,HAMERSMA P J,FORTUIN J M H.Enhancement of the gas-adsorption rate in agitated slurryreactors by gas-adsorbing particles adhering to gas bubbles[J].Chemical Engineering Science,1993,48(12):2 197-2 210.
[68]	BRILMAN D W F,van SWAAIJ W P M,VERSTEEG G F.Heterogeneous mass transfer models for gas absorption inmultiphase systems[J].Chemical Engineering Science,2000,55(15):2 793-2 812.
[69]	DECKWER W D,BURCKHART R,ZOLL G.Mixing andmass transfer in tall bubble columns[J].ChemicalEngineering Science,1974,29:2 177-2 188.
[70]	�ֳ�,��,��,��.��ɢ�ڶ�Һ��ǿ��Һ��ʵ�Ӱ��[J].��ѧ��,2000,28(2):23-33.