苝酰亚胺衍生物的合成及光谱性能研究

摘要

以3,4:9,10-苝四酸二酐为原料,合成了两种新型的苝酰亚胺衍生物:N-(1-己基庚基)-N'-苯基-3,4:9,10-苝四酸二酰亚胺和N-(1-己基庚基)-N'-苯基-1,7-二(4-叔丁基苯氧基)-3,4:9,10-苝四酸二酰亚胺,其结构经¹H NMR和MS表征。用紫外可见吸收光谱和荧光光谱研究了它们的光学性质,研究结果表明苝核海湾区供电子基团的引入,使得苝核的最大吸收波长发生了明显的红移,Stokes位移达到了29 nm。

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	胡晓霞
	刘东志
	李巍
	周雪琴

关键词：苝酰亚胺；合成；光谱

Abstract：

Two novel perylene diimides derivatives, N-(1-hexylheptyl)-N'-phenyl-perylene-3,4:9,10-tetracarboxydiimide and N-(1-hexylheptyl)-N'-phenyl-1,7-di(p-tert-butylphenoxy)-perylene-3,4:9,10-tetracarboxydiimide, were synthesized from 3,4:9,10-perylenetetracarboxylic dianhydride. The structures were characterized by ¹H NMR and MS. The spectra properties were investigated through UV-Vis and fluorescence spectrum, the results showed that the introduction of electron-donating group at the bay area of perylene structure caused obvious bathochromic shift of maximal absorption and a big Stokes shift of 29 nm.

Keywords： perylene diimide； synthesis； spectrum

Received 2014-03-03;

Fund:

国家自然科学基金项目(29676122)。

Corresponding Authors: 周雪琴,E-mail: zhouxueqin@tju.edu.cn。 Email: zhouxueqin@tju.edu.cn

About author: 胡晓霞(1989-),女,硕士研究生,主要研究方向为精细有机合成。

引用本文:

胡晓霞, 刘东志, 李巍, 周雪琴.苝酰亚胺衍生物的合成及光谱性能研究[J]. 化学工业与工程, 2015,32(4): 7-12

Hu Xiaoxia, Liu Dongzhi, Li Wei, Zhou Xueqin.Synthesis and Spectra Properties of Perylene Diimide Derivatives[J]. Chemcial Industry and Engineering, 2015,32(4): 7-12

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