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化学工业与工程 2014, Vol. 31 Issue (6) :1-5    DOI: doi: 10.13353/j.issn.1004.9533.2014.06.001
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焦磷锆钛的合成及其对铯离子的吸附性能
 王学思, 李国兵, 那平
天津大学化工学院,天津 300072
Synthesis of Zirconium Titanium Pyrophosphate and Its Adsorption Behavior for Cesium Ion
 WANG  Xue-Si, LI  Guo-Bing, NA  Ping
School of Chemical Engineering and Technology, Tianjin University, Tianjin 30072, China

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摘要 利用溶胶-凝胶法合成了4价双金属酸盐-焦磷锆钛(ZTPP),采用扫描电镜(SEM)、傅里叶红外光谱(FT-IR)、比表面积及孔结构分析(BET)、热重-差热分析(TG-DTA)等手段对材料进行了分析和表征,结果表明焦磷锆钛是一种具有发达比表面积的无定形多孔材料,且具有很好的稳定性。吸附实验证明,焦磷锆钛随溶液中铯离子初始浓度增高,吸附容量增大,可达1.4 mmol/g;在不同酸度溶液和竞争阳离子存在的情况下可稳定有效的吸附铯离子,吸附容量稳定;通过调整材料用量,其对铯离子的去除率可接近100%。
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王学思
李国兵
那平
关键词铯离子;   磷酸盐;   吸附     
Abstract: Zirconium titanium pyrophosphate (ZTPP), one type of tetravalent bimetallic acid salt, has been synthesized by a sol-gel method. Various characterization methods including FT-IR, SEM, BET and TG-DTA were utilized for the evaluation of the material. The results indicate that ZTPP is an amorphous and porous material with high thermal stability and high surface area. Adsorption experiments demonstrated that adsorption capacity increased with the increasing of initial cesium ion concentration which can reach up to 1.4 mmol/g; adsorption capacity of cesium ion on ZTPP can be effective at a wider pH values from 1 to 13, and coexisting competitive cations have a minimal effect on its extracting ability. The removal rate of cesium ion can reach approximately 100% by adding more material.
Keywordscesium ion;   phosphate;   adsorption     
Received 2013-04-23;
Fund:

国家高技术研究发展计划(863计划)资助项目(2012AA063504)。

Corresponding Authors: 那平,电话:(022)27405967,E-mail: naping@tju.edu.cn。     Email: naping@tju.edu.cn
About author: 王学思(1989-),男,硕士,主要从事重金属水污染方面研究。
引用本文:   
王学思, 李国兵, 那平.焦磷锆钛的合成及其对铯离子的吸附性能[J].  化学工业与工程, 2014,31(6): 1-5
WANG Xue-Si, LI Guo-Bing, NA Ping.Synthesis of Zirconium Titanium Pyrophosphate and Its Adsorption Behavior for Cesium Ion[J].  Chemcial Industry and Engineering, 2014,31(6): 1-5
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