[an error occurred while processing this directive]
化学工业与工程
 首页 |  在线投稿 |  期刊介绍 |  编 委 会 |  投稿指南 |  期刊订阅 |  下载中心 |  出版伦理 |  联系我们 |  English
化学工业与工程 2014, Vol. 31 Issue (3) :72-78    DOI: 10.13353/j.issn.1004.9533.2014.03.012
研究论文 最新目录 | 下期目录 | 过刊浏览 | 高级检索 << | >>
直接液流燃料电池的制备、活化及性能
米南1,韩大量1,黄成德1,张晶2
(1天津大学化工学院,天津 300072; 2中国电子科技集团第十八研究所,天津 300381)
Preparation, Activation and Properties of Direct Liquid Redox Fuel Cell
 MI Nan1, HAN  Da-Liang1, HUANG  Cheng-De1, ZHANG  Jing2
(1School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2Tianjin Institute of Power Sources, Tianjin 300381, China)

摘要
参考文献
相关文章
Download: PDF (2010KB)   HTML ()   Export: BibTeX or EndNote (RIS)      Supporting Info
摘要 采用热压方法制备阳极半膜电极(AHME)用于直接液流氧化还原燃料电池(DLRFC)单体中,研究了热压过程的条件参数对AHME性能的影响。为了使组装后的DLRFC达到最佳性能,采用高温水、恒电流放电以及变电流放电3种方式对其进行活化,研究了恒电流活化过程中活化条件对DLRFC电化学性能的影响。结果表明,最适宜热压条件是120 ℃,以200 kg/cm2的热压压力保压120 s左右。对于DLRFC单体而言,采用放电活化的方式优于高温水活化。恒电流活化方式中的最适宜活化时间、活化温度和活化电流密度分别是3 h、60 ℃和20 mA/cm2
Service
把本文推荐给朋友
加入我的书架
加入引用管理器
Email Alert
RSS
作者相关文章
米南1
韩大量1
黄成德1
张晶2
关键词DLRFC;   阳极半膜电极   热压;   活化;   电化学性能     
Abstract: The influence of hot-pressing procedure on the performance of anodic half membrane electrode (AHME) used in direct liquid redox fuel cell (DLRFC) was investigated. The performance of DLRFCs activated by hot water circulation, constant current discharge and alternating current discharge were studied, respectively, to identify the optimal activation procedure. The dependence of the electrochemical properties of DLRFC on the process conditions of the constant current discharge activation was also studied. The results revealed that the optimal conditions for hot-pressing were being operated at 120 ℃ and under the pressure of 200 kg/cm2 for 120 s. Additionally, the discharge method was preferable to water circulation in activating DLRFC single cell. The activation of DLRFC by constant current discharge was optimized with the operating time, temperature and current density of 3 h, 60 ℃ and 20 mA/cm2, respectively.
Keywordsdirect liquid redox fuel cell (DLRFC);   anodic half membrane electrode (AHME);   hot-pressing   activation;   electrochemical performance     
Received 2013-03-14;
Fund:

天津市自然科学基金项目(11CYBCJC07800)。

Corresponding Authors: 黄成德,电话:(022)27890515,E-mail: cdhuang@tju.edu.cn。     Email: cdhuang@tju.edu.cn
About author: 米南(1987-),女,硕士研究生,现从事燃料电池系统与性能方面的研究。
引用本文:   
米南, 韩大量, 黄成德, 张晶.直接液流燃料电池的制备、活化及性能[J].  化学工业与工程, 2014,31(3): 72-78
MI Nan, HAN Da-Liang, HUANG Cheng-De, ZHANG Jing.Preparation, Activation and Properties of Direct Liquid Redox Fuel Cell[J].  Chemcial Industry and Engineering, 2014,31(3): 72-78
Copyright 2010 by 化学工业与工程