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化学工业与工程 2014, Vol. 31 Issue (3) :56-60    DOI: 10.13353/j.issn.1004.9533.2014.03.009
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锂离子电池用Fe3O4/纳米碳复合材料的制备及性能
方泽炜1,2,乔志军1,2,马倩倩1,2,郑嘉明1,2,王成扬1,2,苗艳丽3,魏蕾3
(1天津大学化工学院,天津 300072; 2天津大学化学化工协同创新中心,天津 300072; 3天津市贝特瑞新能源科技有限公司,天津 301802)
Preparation and Performances of Fe3O4/nanocarbon Hybrids as LIB Anode Materials
 FANG  Ze-Wei1, 2 , QIAO  Zhi-Jun1, 2, MA  Qian-Qian1, 2 , ZHENG  Jia-Ming1, 2, WANG  Cheng-Yang1, 2 , MIAO  Yan-Li3, WEI  Lei3
(1School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;2Synergetic Inovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300072, China;3BTR New Energy Materials Inc., Tianjin 301802, China)

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摘要 以苯甲醇为溶剂和还原剂,溶剂热法一步合成四氧化三铁/石墨烯碳纳米管(Fe3O4/r-GO-CNTs)三元复合材料。X射线衍射仪(XRD)、傅里叶红外光谱(FTIR)、扫描电子显微镜(SEM)和高倍透射电镜(HRTEM)测试显示,Fe3O4纳米晶体的生成与氧化石墨烯的还原是同时发生的,Fe3O4的尺寸约为10 nm,均匀且稳固地生长在r-GO片层和CNTs组成的三维网络结构上。电极材料在0.1 A/g下循环100次之后可逆比容量为840 mA·h/g,循环稳定性明显优于纯Fe3O4电极。
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方泽炜1
2
乔志军1
2
马倩倩1
2
郑嘉明1
2
王成扬1
2
苗艳丽3
魏蕾3
关键词纳米Fe3O4;   Fe3O4/r-GO-CNTs复合材料;   负极材料;   锂离子电池     
Abstract: A one-pot process for preparing Fe3O4/r-GO-CNTs composites has been realized. In the solvethermal process, benzyl alcohol was used as the solvent and reducing agent. The morphology and structure of the composites were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscope (SEM) and high-resolution transmission electron microscope (HRTEM). The results demonstrated that the reduction of graphene oxide and the deposition of Fe3O4 about 10 nm on r-GO-CNTs surface were occurred simultaneously. The cycling stability of the obtained hybrid is better than that of the pure Fe3O4 electrode material. At the current density of 0.1 A/g, after 100 cycles, its reversible discharge capacity still remained 840 mA·h/g.
Keywords Fe3O4 nanoparticles;   Fe3O4/r-GO-CNTs hybrid materials;   anode materials;   lithium ion batteries     
Received 2014-02-20;
Fund:

国家自然科学基金面上项目(51172160); 国家863计划资助项目(2011AA11A232);国家863计划项目(2014AA052301)。

Corresponding Authors: 王成扬,电话:(022)27890481;E-mail: cywang@tju.edu.cn。      Email: cywang@tju.edu.cn
About author: 方泽炜(1990-),男,硕士研究生,研究方向为储能材料。
引用本文:   
方泽炜, 乔志军, 马倩倩, 郑嘉明, 王成扬, 苗艳丽, 魏蕾.锂离子电池用Fe3O4/纳米碳复合材料的制备及性能[J].  化学工业与工程, 2014,31(3): 56-60
FANG Ze-Wei , QIAO Zhi-Jun , MA Qian-Qian , ZHENG Jia-Ming , WANG Cheng-Yang , MIAO Yan-Li, WEI Lei.Preparation and Performances of Fe3O4/nanocarbon Hybrids as LIB Anode Materials[J].  Chemcial Industry and Engineering, 2014,31(3): 56-60
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