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化学工业与工程 2013, Vol. 30 Issue (4) :12-15    DOI:
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芒硝型卤水中盐硝组分对碱法脱除钙镁的影响
 董泽亮, 张琦, 王俐聪, 蔡荣华, 马来波, 黄西平
国家海洋局天津海水淡化与综合利用研究所,天津 300192
Effects of sodium sulfate and sodium chloride on Ca2+、Mg2+ removal from Glauber type brine by sodium hydroxide  and sodium carbonate
 DONG  Ze-Liang, ZHANG  Qi, WANG  Li-Cong, CAI  Rong-Hua, MA  Lai-Bo, HUANG  Xi-Ping
Institute of Tianjin Seawater Desalination and Multipurpose Utilization,State Oceanic Administration,Tianjin 300192,China

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摘要 采用“烧碱纯碱”法,对芒硝型卤水中Ca2+和Mg2+的脱除进行了研究,在常温、两碱用量为理论用量、反应时间为30 min和陈化时间为60 min的条件下详细考察了卤水中氯化钠和硫酸钠含量的变化对Ca2+和Mg2+脱除效果的影响。结果表明,硫酸钠组分对Ca2+的脱除效果影响较大,当硫酸钠含量在30 g/L以下时,Ca2+脱除率在90%以上,硫酸钠浓度增加有利于Mg2+的脱除,但影响不大。氯化钠组分对Ca2+、Mg2+脱除效果的影响相对较小,氯化钠含量增加,Ca2+脱除率明显增加,而Mg2+脱除率略有下降。
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董泽亮
张琦
王俐聪
蔡荣华
马来波
黄西平
关键词硫酸钠   氯化钠   钙镁离子   沉淀     
Abstract: Ca2+、Mg2+ removal from Glauber type brine by sodium hydroxide and sodium carbonate has been studied.The effects of sodium sulfate and sodium chloride on removal efficiency of Ca2+, Mg2+ at room temperature were investigated in detail when addition amount of sodium hydroxide and sodium carbonate was theoretical value,reaction time was 30 min,aging time was 60 min.The experimental results show that the presence of sodium sulfate has large effect on removal efficiency of Ca2+.The removal rate of Ca2+ is more than 90% when the concentration of sodium sulfate is below 30 g/L.The presence of sodium sulfate has good but little effect on removal efficiency of Mg2+.The presence of sodium chloride has small effect on removal efficiency of Ca2+ and Mg2+.When the concentration of sodium chloride increases,the removal rate of Ca2+ increases significantly,but the removal rate of Mg2+ declines slightly.
Keywordssodium sulfate   sodium chloride   calcium and magnesium cation   precipitation     
Received 2012-11-12;
Fund:

中央级公益性科研院所基本科研业务费专项资金项目(K-JBYWF-2011-G14)。

Corresponding Authors: 黄西平,电话:(022)87898171,E-mail:xipinghuang@163.com。     Email: xipinghuang@163.com
About author: 董泽亮(1984—),男,汉,硕士,主要从事海水卤水化学资源利用研究。
引用本文:   
董泽亮, 张琦, 王俐聪, 蔡荣华, 马来波, 黄西平.芒硝型卤水中盐硝组分对碱法脱除钙镁的影响[J].  化学工业与工程, 2013,30(4): 12-15
DONG Ze-Liang, ZHANG Qi, WANG Li-Cong, CAI Rong-Hua, MA Lai-Bo, HUANG Xi-Ping.Effects of sodium sulfate and sodium chloride on Ca2+、Mg2+ removal from Glauber type brine by sodium hydroxide  and sodium carbonate[J].  Chemcial Industry and Engineering, 2013,30(4): 12-15
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