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化学工业与工程 2012, Vol. 29 Issue (4) :58-62    DOI:
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亲水性无定型TiO2/SiO2薄膜及其强化传热性能研究
徐克1,2*,齐春华1,2,冯厚军1,2,吕庆春1,2
(1国家海洋局天津海水淡化与综合利用研究所,天津,300192;2国家海水利用工程技术研究中心,天津,300192)
Hydrophilic Amorphous TiO2/SiO2 Thin Film and Its Application to Falling Film Heat Exchangers
 XU  Ke, QI  Chun-Hua, FENG  Hou-Jun, LV Qing-Chun
(1Institute of Seawater Desalination and Multipurpose Utilization, State Oceanic Adiministration, Tianjin, 300192; 
2National Engineering Technology and Research Center for Seawater Utilization, Tianjin, 300192)

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摘要 采用溶胶-凝胶技术在传热管表面涂覆TiO2/SiO2复合溶胶涂层,并通过优化热处理温度和干湿交替处理工艺,提升涂层的亲水性能和强化传热性能。试验结果显示,在热处理温度为200 ℃时,凝胶涂层以无定型结构为主;热处理试样经过6次干湿交替处理后,即可使表面接触角降低到10 °左右;传热管表面较好的润湿性能,可显著提升降膜式换热器的换热效率。
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徐克
齐春华
冯厚军
吕庆春
关键词海水淡化   降膜传热   表面亲水处理   溶胶-凝胶     
Abstract: The hydrophilic amorphous TiO2/SiO2 thin film was prepared by sol-gel technique for an application to falling film heat exchanger. The crystal structure of TiO2/SiO2 composite xerogel was analyzed by thermogravimetry/differential scanning calorimetry (TG/DSC) and X-ray diffraction (XRD). The heat treatment process and wet/dry cycles were investigated to improve the wettability and heat transfer performance of the thin film, which were characterized by measuring the water contact angle and heat transfer rate of falling film heat exchanger. It showed that the structure of TiO2/SiO2 composite film was amorphous after heat treatment at 200  ℃. When the subsequent wet/dry cycles was 6 or more, the water contact angle of the amorphous film could be decreased to about 10 °. Moreover, the good wettability of heat transfer tube coated with amorphous TiO2/SiO2 thin film would obviously enhance the heat transfer efficiency of falling film heat exchanger.
Keywordsseawater desalination   falling film heat exchange   hydrophilic surface treatment   sol-gel technique     
Fund:

中央级公益性科研院所基本科研业务费专项资金项目(K-JBYWF-2009-G10);国家海洋局海洋公益科研专项项目(201205030)。

引用本文:   
徐克, 齐春华, 冯厚军, 吕庆春.亲水性无定型TiO2/SiO2薄膜及其强化传热性能研究[J].  化学工业与工程, 2012,29(4): 58-62
XU Ke, QI Chun-Hua, FENG Hou-Jun, LV Qing-Chun .Hydrophilic Amorphous TiO2/SiO2 Thin Film and Its Application to Falling Film Heat Exchangers[J].  Chemcial Industry and Engineering, 2012,29(4): 58-62
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