[an error occurred while processing this directive]
化学工业与工程
 首页 |  在线投稿 |  期刊介绍 |  编 委 会 |  投稿指南 |  期刊订阅 |  下载中心 |  出版伦理 |  联系我们 |  English
化学工业与工程 2012, Vol. 29 Issue (4) :1-5    DOI:
化学反应与工艺 最新目录 | 下期目录 | 过刊浏览 | 高级检索 << | >>
羧甲基纤维素钠对纳米银导电墨水性能的影响
 何军, 李莎, 王虹, 邹竞
天津大学化工学院绿色合成与转化教育部重点实验室,天津 300072
Effect of Caboxymethyl Cellulose Sodium on the Properties of Nano Silver Conductive Ink
 HE  Jun, LI  Sha, WANG  Hong, ZOU  Jing
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical 
Engineering and Technology, Tianjin University, Tianjin 300072, Chin

摘要
参考文献
相关文章
Download: PDF (1655KB)   HTML ()   Export: BibTeX or EndNote (RIS)      Supporting Info
摘要 通过液相化学还原法,以聚乙烯吡咯烷酮(PVP)为保护剂,甲醛为还原剂制备得到粒径为70 nm左右的纳米银溶胶。离心洗涤得到高纯度和高浓度的纳米银水溶胶,添加羧甲基纤维素钠(CMC)及其它助剂后,在超声处理下获得了水基导电墨水。该墨水的Zeta电位值为(-42.8±0.96) mV,表明其具有较高稳定性。用热泡式按需喷墨打印机,在相纸基材上印制导电图案,并在150 ℃下加热处理30 min后,其方块电阻值由处理前的38.48 kΩ骤降至0.87 Ω。撕拉试验表明,加入CMC后的纳米银导电墨水,在基材上有很好的附着力。
Service
把本文推荐给朋友
加入我的书架
加入引用管理器
Email Alert
RSS
作者相关文章
何军
李莎
王虹
邹竞
关键词纳米银   导电墨水   稳定性   附着力     
Abstract: The effect of caboxymethyl cellulose sodium (CMC) on the properties of nanosilver conductive ink was investigated. Nanosilver particles with diameter around 70 nm were synthesized by liquid phase chemical reduction method using formaldehyde as reducing agent and polyvinyl pyrrolidone as protective agent. The prepared sample was separated by centrifugation and purified by washing for four times to obtain concentrated and relatively pure silver colliod. After adding CMC and other additives, the stable waterbased conductive ink was obtained under ultrasonic treatment. Here, CMC not only acted as the binder agent but also played a vital role in improving the stability of the prepared ink. The zetapotential of the ink was -42.8±0.96 mV, which indicated that it was quite stable. The pattern was fabricated on photo paper by a dropondemand thermal printer. The sheet resistance of the printed pattern decreased significantly from 30.48 kΩ/□ to 0.87 Ω/□ after heating at 150 ℃ for 30 min. According to tape tear test, the adhesion of the pattern to paper substrate was good. 
Keywordssilver nanoparticle   conductive ink   stability   adhesion     
Fund:

国家自然科学基金资助项目(50673075);天津市科技支撑计划重点项目(11ZCKFGX20200)。

引用本文:   
何军, 李莎, 王虹, 邹竞.羧甲基纤维素钠对纳米银导电墨水性能的影响[J].  化学工业与工程, 2012,29(4): 1-5
HE Jun, LI Sha, WANG Hong, ZOU Jing.Effect of Caboxymethyl Cellulose Sodium on the Properties of Nano Silver Conductive Ink[J].  Chemcial Industry and Engineering, 2012,29(4): 1-5
Copyright 2010 by 化学工业与工程