导电聚合物聚苯胺的化学合成

摘要研究了导电聚苯胺化学合成的工艺条件及碳粉添加剂对聚笨胺产率及电导率的影响。用红外光谱及ＸＰＳ分析确定了化学合成聚笨胺的组成及结构为１／２氧化态的聚苯胺盐，它具有与电化学合成聚苯胺相同的结构和良好的电导率。

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	杨兰生
	许锦茂
	单忠强
	陈卫祥

关键词：聚苯胺化学合成

Abstract： The technological conditions of chemical synthesis of conducting polyaniline were studied.The effect of carbon on yield and conductivity of chemical synthetic polyaniline was also investigated.The composition and structure of polyaniline chemically synthesised was determinded as 1/2-oxide state of polyaniline salt by IR and XPS analysis.This polyaniline has the same structure and conductivity as those of polyaniline electrochemically synthesised.

Keywords： s:polyaniline chemical synthesis conductivity

Received 1994-04-15;

引用本文:

杨兰生，许锦茂，单忠强，陈卫祥.导电聚合物聚苯胺的化学合成[J]. 化学工业与工程, 1994,11(2): 7-12

Yang Lansheng;Xu Jinmao;Shan Zhongqiang;Chen Weixiang.The Chemical Synthesis of Conducting Polyaniline[J]. Chemcial Industry and Engineering, 1994,11(2): 7-12