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化学工业与工程
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��ѧ��ҵ�빤�� 1995, Vol. 12 Issue (3) :15-19    DOI:
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The Structure and Properties of Highly Depersed Catalysts Pd-Cu/C Prepared Via Solvated Metal Atom Impregnation Method
Wu Shihua;Huang Weiping;Zhu Changying;Zhao Weijun;Zhang shuji
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Abstract�� The solvated metal atom impregnation(SMAI)method was employed to Prepare three kind of Pd-Cu/C bimetallic catalysts with diffrent Pd/Cu ratios.The results of XRD and TEM measuments showed that Pd-Cu alloy was formed and the particle size of the alloy was very small,with average diameter<5.0nm.XPS and Auger spectra indicated that both Pd and Cu were in zero-valent state, As Cu contents increased,the catalytical activities of the catalysts in the hydrogenation of mesityl oxide increased, while the selectivities for 4-methyl-2-pentanone were essentially unchanged.
Keywords�� s:metal vapor synthesis;Pd-Cu Catalyst;X-ray; photoelection spectroscopy;activated carbon     
Received 1995-07-15;
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����������Ψƽ���쳣Ӣ����ά����������.���ܼ�������ԭ�ӽ��շ��Ʊ��ĸ߷�ɢ�����ʹ߻���Pd��Cu��C�Ľṹ������[J].  ��ѧ��ҵ�빤��, 1995,12(3): 15-19
Wu Shihua;Huang Weiping;Zhu Changying;Zhao Weijun;Zhang shuji.The Structure and Properties of Highly Depersed Catalysts Pd-Cu/C Prepared Via Solvated Metal Atom Impregnation Method[J].  Chemcial Industry and Engineering, 1995,12(3): 15-19
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