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化学工业与工程 1999, Vol. 16 Issue (4) :13-17    DOI:
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Li_2O·MnO_2-Ag-YSZ氧泵型反应器中NEMCA效应的研究
马忠龙,栾宝林,陈洪钫
天津大学化工学院
Investigation of NEMCA Effect in the Li2OMnO2AgYSZ Catalytic Membrane Reactor
Ma ZhonglongLuan BaolinChen Hongfang
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摘要 本文对Li2O·MnO2-Ag-YSZ氧泵型催化膜反应器中甲烷氧化偶联反应的NEMCA效应进行了研究。考察了稳态电流和反应温度对NEMCA效应的影响,考察了反应气中甲烷含量、反应温度对发生NEMCA效应时的交换电流密度的影响,比较了传递体系和联合体系的交换电流密度与活性过电位的关系。结果表明:高甲烷含量、低反应温度和反应气中引入极少量的O2,可降低三相界面的交换电流密度,有利于NEMCA效应的发生
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马忠龙
栾宝林
陈洪钫
关键词催化膜   氧泵   NEMCA效应   交换电流密度   三相界面     
Abstract: NEMCA effect of OCM was investigated on the Li2OMnO2AgYSZ catalytic membrane in the oxygenpumping reactor.The influence of the steadystate current and reaction temperature on NEMCA effect was investigated,so did the CH4 content in the reaction gas and reaction temperature on the exchange current density when NEMCA took place.The relation of the exchange current density and the active over potential in the transport system was compared to that in the joint system.The results show that the exchange current density in the threephaseboundary is decreased by increasing the content of CH4 in the reaction gas,decreasing reaction temperature and adding small amount oxygen into the reaction gas.Low exchange current density is favorable to the generation of NEMCA effect.
Keywordscatalytic membrane   oxygen pumping   NEMCA effect   exchange current density   threephaseboundary     
Received 1999-10-15;
引用本文:   
马忠龙,栾宝林,陈洪钫.Li_2O·MnO_2-Ag-YSZ氧泵型反应器中NEMCA效应的研究[J].  化学工业与工程, 1999,16(4): 13-17
Ma ZhonglongLuan BaolinChen Hongfang .Investigation of NEMCA Effect in the Li2OMnO2AgYSZ Catalytic Membrane Reactor[J].  Chemcial Industry and Engineering, 1999,16(4): 13-17
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